I've only done one part run through the EE version of ToB, and Rasaad was in my party from the beginning (through SoA), so I don't know if the chapter number makes any difference to his quest. What I know is that his quests have started without a hitch both in BG1 and SoA, irrespective of whether he was recruited early or late in the game, so I would think that if you summon him in the pocket plane in ToB, his quest should start the first time you leave the pocket plane with him in the party.
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