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There are a few roleplay ideas I've come up with but have never executed. While I'm on a cleric kick at the moment, I find the thief ideas to be alluring.
1. Bounty Hunter - Play LN to the hilt. Help the Flaming Fist officer kill Viconia. Make sure that Greywolf doesn't steal your bounty. Go on a personal mission to collect bandit scalps for Officer Vai.
2. Assassin - Like the Bounty Hunter but more ruthless.
3. Thief - Become a Shadow Thief of Amn. Get the Shadow Thief Studded Leather as soon as possible. Once you get to Baldur's Gate, make sure to trespass every building and steal everything! Amass as much gold as possible.
4. Undead Hunter - Better for BG2, but you know what needs to be done. Don't manipulate Bassilus so that you are forced to fight off his skeletons. Don't limit yourself to just undead; werewolves and other creatures that go bump in the night must be destroyed.
What are some of your ideas?