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I'm in the desert town late in ToB, and I've only had one early ocnversation with Sarevok (about him being free to choose his own fate or make the same mistakes). I haven't gotten any others, neither in conjunction with the plot or whatnot. He's been in my party the whole time (Minsc, Jaheira, Viconia, Imoen, and sometimes Rasaad, Hexxat, and Neera). The only thing I can think is that somehow it's conflicting with the Viconia romance culmination, because I have gotten her conversations (and alignment switch) with regularity.