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Are there any characters that every time you bump into them you think "Oh, not that guy! I hate that guy!"
With me it's Drizzt. When I first played BG I knew nothing of the lore of the Forgotten Realms and so hadn't heard of him and right from the start I thought he seemed like a dick. He asks for your help but it's only so he can show off how much better than you he is. And even if you do help him you get nothing for it (except the gnoll treasure he can't be bothered to pick up for himself).
Plus he's got all this cool gear but the only way to get your hands on it is to go heavy on the cheese and for me that breaks any immersion in the game. And even if you do get his gear you are going to end up wielding a sword called Twinkle. I ask you, what kind of loser calls their sword Twinkle?
Drizzt Do'Urden - I hate that guy.